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Several cobalt(III) complexes of the V-hydroxyethyliminodiacetate ion (“heida”) have been prepared. Infrared and nmr studies, as well as exchange studies with D2O, show that the ligand tends to be tridentate and that the alcoholic hydroxyl group does not coordinate. Moreover, the alcoholic group in the complex can be acetylated without destruction of the complex. However, in [Co(en)(heida)]0, the alcoholic OH loses its proton, and the ligand becomes trinegative and tetradentate. © 1974, American Chemical Society. All rights reserved.
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