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Supercapacitors are considered some of the best electrochemical energy storage systems due to their high power and energy density, fast charge–discharge capabilities, and longer cycleability, compared to regular capacitors. In this paper, we report the synthesis of hybrid MnO2/CuS/reduced graphene oxide (MC-rGO) materials via a simple chemical route and characterized them to examine different properties. The focus of this article is to examine the effect of binder concentrations on the electrochemical properties of the supercapacitor electrodes, prepared using the synthesized hybrid materials. We used 5%, 10%, and 15% (wt.%) polyvinylidene fluoride (PVDF) binders to prepare the electrodes. We prepared the slurry of MC-rGO material using synthesized cathode materials, carbon black, and PVDF in 75:10:15, 80:10:10, and 85:10:5 wt.%. The specific capacitance with 5%, 10%, and 15% binders was found to be 176.33 F/g, 161.34 F/g, and 149.55 F/g, respectively, at 0.5 A/g current density. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2025.