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From the report: "Project title: Walking the walk or just talking the talk? An exploratory study of the ways social workers understand social work practice." The report describes the research problem, identifies three reserach questions, and discusses the project outcomes and reporting.
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The HF method uses single determinant to solve Schrödinger equation and obtain molecular orbitals. A variety of post-HF methods such as MP2 and CCSD are needed to treat molecular systems in ground states accurately, while the CIS and EOM-CCSD methods are developed to study excited states. All these methods can write out wavefunction files in single determinant so that the unique electron density distributions of the system at all these calculation levels are available. The quantum theory of atoms in a molecule (QT-AIM) performs density topological analyses and rigorously obtain properties such as net atomic charges and delocalization and localization indices for ground states at HF/CIS and post-HF levels and for excited states at CIS, EOM-CCSD levels. The density functional theory (DFT) develops a larger number of functionals to account for the electron–electron correlation via exchange-correlation potentials, and TD-DFT methods study properties of electronically excited states. The DFT and TD-DFT methods rely on electron density to solve Schrödinger equations and write out final wavefunctions in single determinant format. Therefore, density-based analyses can be also done for a variety of DFT and TD-DFT methods. Along with molecular orbitals, density-based analyses are applied to explain ambident reactivity, to identify bonding characteristics in organic transition metal compounds, and to evaluate the performance of current DFT and TD-DFT methods. © 2023 Elsevier Inc. All rights reserved.
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This chapter explores the case of President Bill Clinton and the Lewinsky scandal as a pivotal moment in the convergence of political, technological, and cultural changes that elevated the presence of gossip and rumor in mainstream news sources, with major, lasting consequences. Throughout the unfolding of the scandal, unconfirmed and often salacious information about what had happened was transmitted among individuals and amplified through the media. The chapter takes a close look at some key elements contributing to such trends, including use of anonymous sourcing, heightened competition between media outlets, and the emergence of new media actors covering American politics and the presidency. An analysis of two specific incidents, involving coverage of allegations there were eyewitnesses to the president’s affair with Monica Lewinsky and that Lewinsky had a dress stained with the president’s DNA in her possession, demonstrates how prominent national news outlets publicized information reflecting weaker reporting standards and conveyed unsubstantiated rumors as news. As the news media devalued itself in cases such as this one, abandoning professional conventions and prioritizing sensational, entertaining content, the public began to no longer trust or rely on such sources to help it interpret events. We continue to see the ramifications of those developments in the present, with widespread belief in fake news, little consensus on what constitute facts or reality, and stark partisan divides about who can be relied upon to transmit the truth of political events. © 2023, The Author(s), under exclusive license to Springer Nature Switzerland AG.
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