Coordination behavior of the N-hydroxyethyliminoacetate ion
Resource type
Authors/contributors
- Horrigan, P. (Author)
- Canelli, R.A. (Author)
- Kashmann, J.R. (Author)
- Hoffmann, C.A. (Author)
- Bauer, R. (Author)
- Boston, D.R. (Author)
- Bailar, J.C. (Author)
Title
Coordination behavior of the N-hydroxyethyliminoacetate ion
Abstract
Several cobalt(III) complexes of the V-hydroxyethyliminodiacetate ion (“heida”) have been prepared. Infrared and nmr studies, as well as exchange studies with D2O, show that the ligand tends to be tridentate and that the alcoholic hydroxyl group does not coordinate. Moreover, the alcoholic group in the complex can be acetylated without destruction of the complex. However, in [Co(en)(heida)]0, the alcoholic OH loses its proton, and the ligand becomes trinegative and tetradentate. © 1974, American Chemical Society. All rights reserved.
Publication
Inorganic Chemistry
Date
1974
Volume
13
Issue
5
Pages
1108-1110
Journal Abbr
Inorg. Chem.
Citation Key
horriganCoordinationBehaviorNhydroxyethyliminoacetate1974
ISSN
00201669 (ISSN)
Archive
Scopus
Language
English
Extra
4 citations (Crossref) [2023-10-31]
Citation
Horrigan, P., Canelli, R. A., Kashmann, J. R., Hoffmann, C. A., Bauer, R., Boston, D. R., & Bailar, J. C. (1974). Coordination behavior of the N-hydroxyethyliminoacetate ion. Inorganic Chemistry, 13(5), 1108–1110. Scopus. https://doi.org/10.1021/ic50135a020
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